Diethylene Glycol Methyl Ethyl Ether
BOXA SOLVENTS
Butanal
Diethylene Glycol Methyl Ethyl Ether
Specifications
product_name Diethylene glycol methyl ethyl ether
CAS_number 1002-67-1
formula C6H14O3
molar_mass 134.17 g/mol
boiling_point 193 °C
melting_point -85 °C
density 0.973 g/cm³
refractive_index 1.421
flash_point 84 °C
viscosity 3.5 mPa·s
vapor_pressure 0.07 mmHg at 25°C
solubility_in_water Miscible
autoignition_temperature 265 °C
appearance Colorless liquid
odor Mild
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Frequently Asked Questions
What is Diethylene glycol methyl ethyl ether, and what are its primary uses?

Diethylene glycol methyl ethyl ether, often abbreviated as DEGMEE, is an organic compound with notable applications across various industries. This clear, colorless liquid is part of the glycol ether family, known for its excellent solvency properties, moderate evaporation rate, and versatility in formulation processes. Glycol ethers like DEGMEE are indispensable in the manufacturing of paints, inks, coatings, and cleaning products due to their efficacy in dissolving water-insoluble substances and enhancing the performance characteristics of end products. Among its primary uses, DEGMEE is found in the formulation of water-based coatings where it serves as a coalescing agent. Coalescing agents are crucial in waterborne paints because they help in reducing the minimum film formation temperature (MFFT), ensuring a smooth, defect-free film upon drying. The proper balance of viscosity and evaporation rate attributed to DEGMEE is instrumental in achieving optimal film properties. In the cleaning products industry, DEGMEE acts as an effective solvent for greases, oils, and other contaminants due to its miscibility with water and many organic substances. Its cleaning ability is enhanced by its relatively low odor compared to other solvents, making it a preferred choice in applications where user experience and safety are of paramount importance. In addition to its industrial utility, DEGMEE is noted for its role in chemical synthesis, serving as a reaction medium or process solvent in the production of various chemical intermediates. Its stability under a range of conditions and compatibility with numerous chemicals render it an attractive choice for complex synthetic pathways. Given its multifunctionality and safety profile, DEGMEE represents a crucial component in products and processes across extensive sectors, from everyday consumer goods to specialized industrial applications, demonstrating its versatility and indispensable role in modern manufacturing.

What are the safety considerations when handling Diethylene glycol methyl ethyl ether?

When handling Diethylene glycol methyl ethyl ether (DEGMEE), it is imperative to be aware of the associated safety considerations to ensure a safe working environment. As with many industrial solvents, DEGMEE can pose certain health risks if proper precautions are not taken. The compound is known to be an irritant, particularly to the eyes and skin. Inhalation or direct contact with large quantities may result in adverse health effects, thus necessitating the adoption of comprehensive safety measures during handling and use. Personal Protective Equipment (PPE) is a primary line of defense when working with DEGMEE. It is recommended to wear safety goggles to prevent eye exposure, as well as gloves and protective clothing to minimize skin contact. In workplaces with potential exposure to vapors, appropriate respiratory protection or well-ventilated areas should be utilized to reduce inhalation risks. Employers should implement engineering controls, such as fume hoods or localized ventilation systems, to decrease airborne concentrations of the ether. Beyond personal protection, understanding the compound's storage requirements is critical. DEGMEE should be kept in tightly sealed containers away from direct sunlight, heat sources, and incompatible substances such as strong oxidizing agents. Always store it in a cool, dry, and well-ventilated space to maintain product integrity and prevent hazardous conditions. Discussing spill and leak procedures is essential, as accidental releases of DEGMEE necessitate immediate action. Prompt containment and cleanup using absorbent materials, followed by adequate disposal in accordance with local regulations, are necessary to prevent environmental contamination and mitigate health risks. Emergency showers and eye-wash stations should be accessible in areas where DEGMEE is utilized, providing immediate aid in case of accidental exposure. Ultimately, understanding and respecting the substance's safety data sheet (SDS) is vital for maintaining informed practices. The SDS provides detailed information—ranging from potential hazards and first-aid measures to firefighting procedures and handling recommendations—which all personnel involved in handling the compound should be well-acquainted with.

How does Diethylene glycol methyl ethyl ether benefit water-based coatings?

Diethylene glycol methyl ethyl ether (DEGMEE) plays a pivotal role in enhancing water-based coatings, acting primarily as a coalescing agent and solvent that contributes to superior film formation and application properties. Understanding its benefits in this context requires appreciating the challenges posed by formulating waterborne coatings and how DEGMEE addresses these challenges effectively. In water-based coatings, film formation is crucial for achieving an even, durable, and aesthetically pleasing finish. The process involves the coalescence of binder particles into a continuous film as the water and other solvents evaporate. DEGMEE aids this process by lowering the Minimum Film Formation Temperature (MFFT) of the coating. Lowering the MFFT is essential in enabling film formation at ambient temperatures, avoiding defects such as cracking or poor adhesion that occur when the MFFT exceeds the application temperature. DEGMEE's molecular structure grants it an optimal balance of hydrophobic and hydrophilic properties, improving the solubilization of various coating components and enhancing compatibility. Its presence in a formulation reduces surface tension, improving wetting properties. This leads to better substrate coverage, leveling, and uniformity in the final dried film. Additionally, the moderate evaporation rate of DEGMEE ensures effective film coalescence without significantly prolonging drying times, balancing process efficiency and product performance. In terms of environmental and safety considerations, DEGMEE contributes to the formulation of low-VOC (volatile organic compound) coatings, an increasingly important market segment driven by regulatory and consumer demands for safer, eco-friendly products. Many conventional solvents release high levels of VOCs, which are harmful to human health and contribute to atmospheric pollution. By incorporating DEGMEE, manufacturers can develop coatings that meet stringent VOC regulations without sacrificing performance quality. Moreover, DEGMEE's relatively low odor compared to other volatile solvents improves user experience during application, reducing the need for protective measures and allowing use in more sensitive environments. Thus, DEGMEE's role extends beyond merely serving as an ingredient; it is integral to achieving balanced performance, environmental compliance, and user safety in modern water-based coating formulations, making it a key asset for formulators in an increasingly eco-conscious industry.

What environmental impact does Diethylene glycol methyl ethyl ether have?

Diethylene glycol methyl ethyl ether (DEGMEE) comes with certain environmental considerations that warrant careful analysis and management, especially as industries seek to balance functionality with environmental stewardship. Understanding DEGMEE's environmental impact begins with examining its behavior in various environmental compartments, including air, water, and soil. DEGMEE is not highly volatile, yet it can still be released into the atmosphere during production, application, and disposal processes. Its relatively low volatility compared to other solvents may mitigate extensive atmospheric dispersion, yet local concentrations could pose risks, particularly in areas with inadequate ventilation or during accidental spills. It is less photochemically reactive, implying that its direct contribution to photochemical smog formation or ozone depletion is limited. However, responsible emissions management is still crucial to prevent localized environmental degradation and workplace exposure. In aquatic ecosystems, DEGMEE exhibits moderate water solubility, leading to potential contamination of water bodies if not disposed of properly. Biodegradation studies suggest that DEGMEE is readily biodegradable under aerobic conditions, highlighting a potential for natural breakdown over time which mitigates long-term accumulation in water bodies. Despite this biodegradability, the immediate effects on aquatic life must not be underestimated, as acute exposure can be detrimental to aquatic organisms. Thus, effluent treatment and adherence to waste disposal guidelines are imperative to minimize ecological disruption. Terrestrial impact primarily revolves around soil exposure, where DEGMEE is reasonably expected to exhibit minimal bioaccumulation potential due to its chemical properties. Its mobility in the soil environment depends on local conditions, such as pH and organic matter content, yet its overall degradation behavior suggests a limited long-term risk of soil contamination barring heavy, repeated exposure. Regulatory frameworks increasingly emphasize the sustainable use and lifecycle management of chemical solvents like DEGMEE to mitigate their environmental footprints. Adherence to REACH (Registration, Evaluation, Authorisation, and Restriction of Chemicals) regulations within the European Union, or corresponding legislative standards in other jurisdictions, forms a foundation for responsible handling and disposal practices. Companies are encouraged to conduct regular environmental impact assessments, integrate pollution prevention strategies, and explore greener alternatives whenever feasible as part of comprehensive environmental management systems. Through conscious handling, prudent use, and pro-active policy compliance, industries employing DEGMEE can significantly reduce its environmental impact, supporting the goals of sustainable development and ecological preservation.

How does Diethylene glycol methyl ethyl ether compare to other solvents in performance?

Diethylene glycol methyl ethyl ether (DEGMEE) occupies a distinctive niche within the spectrum of industrial solvents, leveraging its unique physical and chemical properties to offer advantages in performance relative to traditional and more volatile solvents. Its comparison with other solvents requires examining its efficacy, safety, environmental impact, and versatility across various applications. Performance-wise, DEGMEE excels in its ability to act as a solvent and coalescing agent, particularly in waterborne coatings, inks, and cleaning products. When pitted against conventional high-volatility solvents, DEGMEE presents a moderate evaporation rate, which is integral to controlled drying processes crucial for achieving desired film characteristics in coatings and inks. Its evaporation dynamics prevent defects such as cracking or bubbling, common with faster-drying alternatives. In cleaning formulations, DEGMEE exhibits outstanding solvency for grease, oils, and waxes, combined with the advantage of a lower odor profile compared to similar hydrocarbon-based solvents. Its semi-hydrophilic nature enhances its ability to dissolve both polar and non-polar substances due to balanced hydrophilic-lipophilic attributes, facilitating its use in multi-component systems where diverse ingredient compatibility is necessary. Safety and environmental factors also significantly differentiate DEGMEE. It embodies a more favorable toxicity and safety profile than many aromatic or chlorinated hydrocarbons, reducing the potential for acute health hazards and enabling its safer use in consumer-facing products. Compliance with increasingly stringent environmental regulations is another area where DEGMEE has an edge: it aids in formulating products with reduced volatile organic compound (VOC) emissions, aligning with global sustainability trends and regulatory mandates for lower VOC content. In processes concerned with reducing human exposure risks and environmental impacts, DEGMEE provides an efficacious alternative to highly hazardous options. In some industrial applications, however, the specific needs may lead to the selection of alternative solvents based on criteria such as cost, availability, or specific solubility requirements not completely met by DEGMEE. While options like acetone or other glycol ethers might offer faster evaporation rates or slightly different solvation parameters matching particular chemical behaviors, DEGMEE's overall performance versatility often renders it an optimal compromise in cases necessitating a blend of effective film formation, environmental compliance, and operational safety. This balancing act places DEGMEE as a noteworthy contender among industry solvents, encapsulating a broad array of functional and compliance-related benefits necessary for modern formulation needs.

What factors influence the selection of Diethylene glycol methyl ethyl ether in formulations?

The selection of Diethylene glycol methyl ethyl ether (DEGMEE) in formulations is governed by an intricate balance of performance, safety, regulatory, and economic factors. Each factor plays a role in determining when and how DEGMEE is used to achieve the desired properties in end products while meeting industry standards and consumer expectations. Performance considerations are paramount in the selection process. DEGMEE's utility as a coalescing agent and solvent is largely due to its ability to lower the Minimum Film Formation Temperature (MFFT) in water-based coatings and paints. This function is crucial for ensuring film integrity and smoothness at ambient temperatures, a requirement for high-quality surfaces in architectural and industrial applications. The balance of DEGMEE's evaporation rate—neither too rapid to cause surface defects nor too slow to delay drying—is optimal for many applications cut across various industries, from coatings to formulations requiring deep-cleansing properties, such as cleaning agents. Its dual solubility with water and organic compounds means DEGMEE can facilitate the dissolution and application of diverse substances, a versatility that makes it an attractive option for multipurpose use scenarios. Safety is another critical factor shaping its selection. DEGMEE's lower volatility and relatively benign toxicity profile compared to other solvents enhances workplace safety and reduces consumer risk during and after application. Regulatory compliance compounds the safety consideration, with DEGMEE being part of formulations seeking reduced volatile organic compound (VOC) content to meet environmental protection standards, including state and national levels. Lower VOC formulations are particularly valued in sensitive sectors and locations where air quality considerations are prominent. Economically, the cost-effectiveness of DEGMEE as a functional ingredient compared to alternatives is significant. Though sometimes costlier than basic solvents, its multifunctionality can lead to material reduction of additional additives, optimizing formulation complexity and cost over the entire lifecycle of the product. Stability and shelf life conferred by DEGMEE further reinforce its value proposition by reducing wastage and prolonging the usability of stored products. Furthermore, the geographical availability and supply chain considerations for raw materials also influence its selection, sometimes directing choices based on logistic feasibilities and the presence of local regulations and incentives promoting the use of environmentally responsible solvents. These various factors collectively guide formulation specialists in determining whether DEGMEE is the optimal solution, signaling not only a technical fit but also compliance with evolving safety, regulatory, and market standards that stress holistic evaluation over sheer technical functionality.
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